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Cyclic trinuclear gold(I) complexes with chiral 3,5‐diarylpyrazolate ligands have been synthesized and characterized with the aim of obtaining helical columnar liquid‐crystal phases as a way to control the stacking geometry and orientation of the trigold metallacycle in the bulk phase. The compounds bear n‐decyloxy‐ and/or (S)‐3,7‐dimethyloctyloxy terminal groups in a number varying from twelve to...
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