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The solution molecular structure and the electronic and magnetic properties of the heme pocket of the cyanomet complex of the isolated β-chain of human adult hemoglobin, HbA, have been investigated by homonuclear 2D 1 H NMR in order to assess the extent of assignments allowed by 1 H NMR of a homo-tetrameric 65-kDa protein, to guide the future assignments of the heterotetrameric complex...
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