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Zwei Schritte genügen: Ein sehr einfacher zweistufiger Zugang zu polysubstituierten Cyclopentenonen aus endständigen Alkinen, [M(CO)6] und Bromalkenen wird beschrieben. Das Protokoll ist eine Alternative zur Pauson‐Khand‐Reaktion und lässt sich auf verschiedenste Bromalkene anwenden. Die enantiomerenreinen Cyclopentenon‐Produkte können mit einem vollständig C‐substituierten quartären Stereozentrum...
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