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The hitherto elusive disilavinylidene (H2SiSi) molecule, which is in equilibrium with the mono‐bridged (Si(H)SiH) and di‐bridged (Si(H2)Si) isomers, was initially formed in the gas‐phase reaction of ground‐state atomic silicon (Si) with silane (SiH4) under single‐collision conditions in crossed molecular beam experiments. Combined with state‐of‐the‐art electronic structure and statistical calculations,...
Das bisher unbekannte Disilavinyliden‐Molekül (H2SiSi), das hier vor seinem differenziellen Reaktionsquerschnitt abgebildet ist, wird in der Gasphasenreaktion von atomarem Silicium mit Silan (SiH4) gebildet und tritt im Gleichgewicht mit den monoverbrückten Si(H)SiH‐ und diverbrückten Si(H2)Si‐Isomeren auf. Wie R. I. Kaiser, A. H. H. Chang, J. F. Stanton et al. in ihrer Zuschrift auf S. 1284 zeigen,...
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