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The triafulvene molecule (c‐C4H4)—the simplest representative of the fulvene family—has been synthesized for the first time in the gas phase through the reaction of the methylidyne radical (CH) with methylacetylene (CH3CCH) and allene (H2CCCH2) under single‐collision conditions. The experimental and computational data suggest triafulvene is formed by the barrierless cycloaddition of the methylidyne...
Triafulven (C4H4), das einfachste Mitglied der Fulvenfamilie, wird als naszierendes Produkt bei der Reaktion von Methylidin‐Radikalen (CH) mit Allen (CH2CCH2) und Methylacetylen (CH3CCH) gebildet. Wie A. M. Mebel, R. I. Kaiser und Mitarbeiter in ihrem Forschungsartikel auf S. 15634 zeigen, wird die Bildung von Triafulven durch die Cycloaddition des CH‐Radikals an ungesättigte C3H4‐Bindungen und die...
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