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Zwei Metalle sind besser als eines: Ein cyclisches 1,1‐Dimagnesiosilan, ein 1,1‐Di(chlormagnesio)silan und ein 1,1‐Di(chlorzincio)silan wurden mithilfe von Transmetallierungen synthetisiert (siehe Schema; THF=Tetrahydrofuran) und röntgenographisch charakterisiert. Das cyclische 1,1‐Dimagnesiosilan wurde in Redoxreaktionen untersucht, die zu einem lithiumsubstituierten Silylradikal und einem vicinalen...
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