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The binary metal oxide, CuOCeO 2 /γ-Al 2 O 3 , has been compared with the single oxide components CuO/γ-Al 2 O 3 and CeO 2 /γ-Al 2 O 3 for toluene total oxidation. The nature of the active sites was determined by means of several spectroscopic techniques, while the transient response technique TAP (Temporal Analysis of Products) was used...
The total oxidation of toluene was studied over a CuO–CeO 2 /γ-Al 2 O 3 catalyst in a Temporal Analysis of Products (TAP) setup in the temperature range 673–923K in the presence and absence of dioxygen and at various degrees of reduction of the catalyst. The reaction rate significantly decreases over a mildly reduced catalyst. Under vacuum and at high-temperature, mild reduction...
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