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Ferrocenophane derivatives 3 act as electrochemical sensors of Mg 2+ ions: a new redox peak appears in the CVs anodically shifted compared to the E 1/2 of the free receptors by 268-382 mV. Receptors 3a, 3c and 3d are selective for Mg 2+ , whilst 3b is also responsive to Ca 2+ ion (302 mV shift). Receptor 3c also gave a highly visual output response...
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