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A new series of group 6 carbonyl complexes of N-[(2-pyridyl)methyliden]-α (or β)-aminonaphthalene (α/β-NaiPy) are described in this work. The complexes are formulated as cis-[M(CO) 4 (α/β-NaiPy)] by elemental, mass and other spectroscopic data. The complexes show emission spectra at room temperature and their quantum yield lies between 0.4 and 0.5. All the complexes exhibit negative solvatochromism...
A new series of Cr(0)- and Mo(0)-carbonyl complexes of 1-alkyl-2-(naphthyl-α/β-azo)imidazoles (α/β-NaiR′) are described in this work. The complexes are formulated cis-[M(CO) 4 (α/β-NaiR′)] by elemental, mass and other spectroscopic data. The complexes are stable and exhibit emission spectra at room temperature. Cyclic voltammetry shows two metal centred oxidations, M + /M 0 ...
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