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Two MnIV complexes of general formula [Mn(salbutO)X] [H3salbutO = 1,4‐bis(salicylidenamino)butan‐2‐ol, 1: X = N3, 2: X = SCN] have been prepared and structurally characterized. The crystal structure of 1 shows that salbutO3– acts as a pentadentate ligand through the two phenolato‐O, two imino‐N, and one alcoholato‐O atoms, and the sixth coordination position is occupied by the azido‐N atom, resulting...
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