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Phosphorus‐containing multiple‐bond systems have received great interest in various applications but often require elaborate syntheses and special precursors. In this paper, we describe simple methods for the synthesis of imidazoyl phosphinidenes and bis(imidazolyl)–P(I) halides from elemental phosphorus or the heptaphosphides Na3P7 and (Me3Si)3P7. The reactions of imidazolium salts with KOtBu and...
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