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The structural features of a representative set of five complexes of octyl α‐ and β‐mannosides with some members of a new generation of chiral tripodal diaminopyrrolic receptors, namely, (R)‐5 and (S)‐ and (R)‐7, have been investigated in solution and in the solid state by a combined X‐ray, NMR spectroscopy, and molecular modeling approach. In the solid state, the binding arms of the free receptors...
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