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Four new ternary rare-earth-metal carbometalates, Nd 2 [MoC 2 ] and RE 2 [WC 2 ] with RE=Ce, Pr, Nd, have been synthesized by argon arc melting and subsequent heat treatment at 1170K for 30 days. They crystallize with the Pr 2 [MoC 2 ] structure type with isolated C 4− species and are typical carbometalates with (i) low metal-to-carbon ratio,...
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