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The L 3 -edge X-ray absorption spectrum of the aqua trivalent Cm ion in aqueous solution exhibits a double photoexcitation involving 2p and 4f electrons. The resonance structure of the multielectron excitation reveals a shake-up process at 508.1±10eV. The data indicate a monotonic increase of the [2p4f] excitation energy between elements of sixth period (Au, Hg, Pb and Bi) and the early actinides...
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