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Solvothermal synthesis of a highly porous metal–organic framework (PMOF) of Cu(II) had been achieved with a bent tetracarboxylate linker, L4− incorporating an –NH2 group in the middle. The design of the linker afforded paddle-wheel secondary building unit (SBU) with metal bound solvent molecules. Upon activation by heating, the overall integrity of the structure remained intact with the result of...
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