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A new aluminoborate, [C 5 H 6 N][AlB 12 O 14 (OH) 12 ], has been hydrothermally synthesized at 200°C. The single-crystal diffraction study reveals that it crystallizes in space group C2/c. It consists of aluminoborate clusters [AlB 12 O 14 (OH) 12 ] − and counterions [C 5 H 6 N] + . The aluminoborate cluster...
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