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A blue luminescent dichlorido-bridged dinuclear copper(II) (S=1/2) complex, [Cu II2 (HL) 2 (μ-Cl) 2 ]·2H 2 O, 1a was synthesized with the 1:1 reaction of the acyclic tridentate salicylaldehyde 2-pyridyl hydrazone ligand, HL, 1. The complex 1a displays multiple bands in the visible region (400–470nm). The association constant (K ass , UV–Vis) was found to...
New luminescent mononuclear and dinuclear copper(II) (S=1/2) complexes [Cu(HL)(H 2 O) 2 ](ClO 4 ) 2 (1a) and [Cu 2 (HL) 2 (μ-SO 4 ) 2 ]·2H 2 O (1b) were synthesized with the acyclic tridentate pyridine-2-carboxaldehyde-2-pyridylhydrazone ligand, HL (1). Interestingly, the mononuclear complex 1a can be converted into the disulfate...
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