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M‐M‐Bindung trifft Zweifachkoordination: Systeme mit Metall‐Metall‐Bindungen sind für die anorganische Chemie von großem Interesse. Eine neue Veröffentlichung beschreibt das erste Beispiel einer Metall‐Metall‐Bindung an ein zweifach koordiniertes Übergangsmetallzentrum (siehe Struktur; Fe orange, O rot, C grau). Die Metall‐Metall‐Bindung in diesem „xenophilen Komplex“ ist am besten als dative Bindung...
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