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New ligands incorporating carboranyl units in organic fragments NS2 (pyridine-dithia) or S′S2 (thiophene-dithia) have been synthesized. The closo species of these ligands were obtained by the reaction of sodium thiolate-o-carborane with the corresponding difunctional electrophile derivatives of pyridine or thiophene. Partial degradation of the closo species derivatives of pyridine was successfully...
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