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The electrochemistry and electrochemiluminescence of two clusters [(tmeda)6Zn14-xMnxSe13Cl2] (tmeda=tetramethylethylenediamine, x=0 and 6) and their correlation to the spectroscopy and structures were investigated. It was discovered that these chalcogenide clusters underwent irreversible redox reactions and therefore emitted very weak ECL in the route of radical annihilation. ECL enhancement was explored...
1,1′-Bis(trimethylsilylseleno)ferrocene has been used to synthesize the anionic cluster [Ag4(fcSe2)3]2− $$\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle-}$}}{2} $$ . In $$\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle-}$}}{2} $$ , a non-bonded tetrahedron of Ag atoms is stabilized by three bidentate ferrocenyldiselenolate groups, which bridge the edges of the tetrahedron in...
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