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Raman spectra of cis-Fe(1,10-phenanthroline) 2 (NCS) 2 and trans-Fe(pyridine) 4 (NCS) 2 are recorded at variable temperature and pressure and used to characterize these complexes via the vibrational modes of the [NCS] − ligands. Vibrational frequencies of the [NCS] − anion in KNCS are 2052, 748 and 484cm −1 for the ν(C–N) stretching, ν(C–S) stretching...
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