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A family of porous magnets of [M 3 (HCOO) 6 ] (M=Mn, Fe, Co and Ni) with open diamond framework based on M-centred MM 4 tetrahedral nodes, can be prepared by conventional solution chemistry method. They display permanent porosity, stability for thermal treatment, guest removal, and guest inclusion for a wide spectrum of both polar and non-polar guests of different size. The...
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