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Supramolecular chemistry is 'chemistry beyond the molecule' - the chemistry of molecular assemblies and intermolecular bonds. It is one of today's fastest growing disciplines, crossing a range of subjects from biological chemistry to materials science; and from synthesis to spectroscopy. Supramolecular Chemistry is an up-to-date, integrated textbook that tells the newcomer to the field everything...
Treatment of the ruthenium(IV) complex [{Ru(η 3 : η 3 -C 10 H 16 )Cl(μ-Cl)} 2 ] (1) with two equivalents of silver(I) selenocyanate gives the new dimeric compound [{Ru(η 3 :η 3 C 10 H 16 )Cl(μ-SeCN)} 2 ] (2). Although two diastereoisomers are observed in solution an X-ray structure determination reveals...
Treatment of the ruthenium(IV) complex [{Ru(η 3 :η 3 -C 10 H 16 )Cl(μ-Cl)} 2 ] (3a) with [PPh 4 ]Cl in CH 2 Cl 2 at room temperature results in the immediate formation of an orange solution of the anionic trichloro complex [PPh 4 ][Ru(η 3 :η 3 -C 10 H 16 )Cl 3 ] (4a)...
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