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In article number 1903432, David Beljonne, Paolo Samorì, and co‐workers demonstrate how common solvent molecules could tune the electronic and optical properties of few‐layer black phosphorus. The physisorption of solvent molecules is shown to modulate the charge carrier density, field effect mobility, and Raman peak shift of black phosphorus, originating from charge transfer and molecular dipole...
Black phosphorus (BP) is recently becoming more and more popular among semiconducting 2D materials for (opto)electronic applications. The controlled physisorption of molecules on the BP surface is a viable approach to modulate its optical and electronic properties. Solvents consisting of small molecules are often used for washing 2D materials or as liquid media for their chemical functionalization...
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