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The Bergman cyclization (BC), the archetypical cycloaromatization reaction, can thermally or photochemically transform acyclic conjugated closed‐shell reactants (enediynes) into cyclic aromatic reactive intermediates (diradicals). This chapter summarizes the key electronic features, scope, and limitations of the photo‐BC. BC and related reactions find numerous practical applications, of which DNA...
Plasma discharges generated by moderate frequency, low energy pulses in a flowing carrier gas with liquid water have been shown capable of producing hydrogen peroxide at moderately high energy yields. The leading hypothesis for the success of this production method is that free elections produced by the plasma in the gas phase dissociate vaporized water molecules into hydroxyl radicals and hydrogen...
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