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Thiadiazolobenzoimidazole (TBI) acceptor was designed in order to increase the electron-withdrawing ability of 2,1,3-benzothiadiazole (BT). The key feature of TBI is the three electron deficient imine groups, rendering it a stronger acceptor than BT. Three TBI-containing compounds TBI-a to TBI-c were synthesized by reaction between 5,6-diamino-2,1,3-benzothiadiazole analogue and the corresponding...
A redox-active, near-infrared absorbing dinuclear ruthenium complex was incorporated into the mainchain of polyimides using a two-stage polymerization method. The polyimides show high thermal stability with a decomposition temperature range from 172 to 248 °C and glass transition temperature of 97–180 °C, depending on the dianhydride monomer used. The polyimides are redox active, electrochromic at...
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