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Two new metal–organic frameworks (MOFs) [Co(AIA)(3-bpdh), Mn(AIA)(3-bpdh)], featuring 2-dimensional layer network topologies are successfully assembled by the solvent diffusion method as CoII and MnII isostructural MOFs, hereafter, 1Co and 1Mn. Moreover, a series of micro-crystals of these two kinds of MOFs with different morphologies and sizes are also obtained by adjusting the synthesis systems...
Two new isostructural metal–organic coordination polymers [{M(H2O)5}2(μ-4-bpdh)(oba)]∞ (M=Co, Ni), 1Co and 2Ni, respectively, were constructed from 4-bpdh (2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene) and oba (4,4′-oxybis(benzoic acid)) in a MeOH–H2O solvent system. The Co (Ni) ion was located in a hexa-coordinate environment surrounded by five aqua ligands and one 4-bpdh ligand, which bridged two...
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