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The local structure of a lead‐free piezoelectric is reported by Dean S. Keeble and co‐workers on page 185. Pair distribution function analysis of Na1/2Bi1/2TiO3 is utilized to reveal the complex behavior of the Bi3+ and Na+ cations, resolving the average structure of the two mixed site cations independently. In particular, the authors observe a “bifurcated” polarization rotation of the bismuth cations,...
ABO3 perovskite‐type solid solutions display a large variety of structural and physical properties, which can be tuned by chemical composition or external parameters such as temperature, pressure, strain, electric, or magnetic fields. Some solid solutions show remarkably enhanced physical properties including colossal magnetoresistance or giant piezoelectricity. It has been recognized that structural...
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