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Moisture sorption, glass transition temperature (T g ) and morphology of ultra thin poly(chloro-p-xylylene) (parylene-C) are greatly influenced by geometrical confinement effects. For film <50nm, the equilibrium moisture saturation is a decreasing function of film thickness. However, the T g of film <50nm is about 10°C higher than thicker films. The above phenomena are attributed...
The thermal behavior of a series of polybenzoxazines based on aniline and various phenols is examined under both inert and oxidative environments. Under an inert environment, the various phenols substantially affect the char yield of polybenzoxazines without altering the mechanism of Mannich base cleavage. Under an oxidative environment, the various phenols have a significant influence on the degradation...
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