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The potential implementation of ruthenium‐based catalysts in polyvinyl chloride production via acetylene hydrochlorination is hindered by their inferior activity and stability compared to gold‐based systems, despite their 4‐fold lower price. Combining in‐depth characterization and kinetic analysis we reveal the superior activity of ruthenium nanoparticles with an optimal size of 1.5 nm hosted on nitrogen‐doped...
Dünnwandige hohle Kohlenstoff‐Nanokapseln mit einem hydrophoben Inneren und guten Dispersionseigenschaften in Wasser können in zwei Schritten synthetisiert werden: Erst werden Metallnanopartikel, die mit einigen Schichten graphenartigem Kohlenstoff beschichtet wurden, an deren Außenseite selektiv mit einem kovalent gebundenen hydrophilen Polymer modifiziert. Dann wird der Metallkern durch eine Säurebehandlung...
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