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Light-induced valence tautomerism (LIVT) and the relaxation process of a mononuclear complex, [Co(phen)(3,5-DTBSQ)(3,5-DTBCat)] (1) (phen=1,10-phenanthroline, 3,5-DTBSQ=3,5-di-tert-butyl-semiquinone, 3,5-DTBCat=3,5-di-tert-butyl-catechol) were investigated by monitoring the ESR signal of the semiquinonate radical both in powder sample and in the sample diluted in butyronitrile or benzene glass matrix...
A novel Fe(III) spin-crossover complex, [Fe(qsal) 2 ][Ni(dmise) 2 ]·2CH 3 CN 1 [qsalH=N-(8-quinolyl)-salicylaldimine, dmise=4,5-dithiolato-1,3-dithiole-2-selone] was prepared. The magnetic susceptibility measurements revealed 1 exhibited a cooperative spin transition with a thermal hysteresis loop of 15K. The high and the low temperature structures of 1 indicated three-dimensional...
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