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A microporous coordination polymer formulated as {[Cu(L) 2 ]·(DMF) 2 } n (1) has been prepared by the direct reaction of copper nitrate with 6-quinolinecarboxylic acid (HL) in DMF. X-ray single crystal diffraction of 1 reveals that the [Cu 2 (COO) 4 ] secondary building units are interconnected by the bridging L ligands to generate a layered framework with the...
Reactions of Fe II , Co II , Ni II , and Zn II salts with 6-quinolinecarboxylic acid (HL) under the hydrothermal conditions afford three monomeric complexes [M(L) 2 (H 2 O) 4 ] (M=Fe II for 1, Co II for 2, and Ni II for 3) and a 1-D polymeric species {[Zn(L) 2 (H 2 O)]·H 2 O} n (4). The...
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