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A new three-dimensional terbium-carboxylate framework [Tb 4 L 3 (H 2 O) 9 ]·7H 2 O (1) [(H 4 L=4,4′-(hexafluoroisopropylidene)diphthalic acid)] has been hydrothermally synthesized and structurally characterized. The framework contains Tb 2 and Tb 4 clusters, and exhibits an unprecedented 4-nodal (3,4,5,8)-connected topology. In addition,...
Twenty one ternary complexes of lanthanide with 3,5-di-tert-butyl-γ-resorcylic acid (L) and seven different substituted pyridine-N-oxides (L 1–7 ), with compositions of REL 3 L 1–72 ·nH 2 O (RE=Nd, Gd, Er; L 1 =4-picoline-N-oxide; L 2 =4-phenyl-pyridine-N-oxide; L 3 =pyridine-N-oxide; L 4 =3-picoline-N-oxide; L 5 =quinoline-N-oxide;...
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