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Klassisch oder nicht? Die Metallionen quadratisch‐planar koordinierter d8‐Komplexe können als Lewis‐Säuren oder ‐Basen mit H2O‐Molekülen in axialen Positionen wechselwirken. Ab‐initio‐Rechnungen zufolge bilden neutrale PtII‐Komplexe Wasserstoffbrücken mit H2O, in denen PtII als Lewis‐Base auftritt. Solche nichtklassischen OH⋅⋅⋅Pt‐Brücken wurden nun in Kristallen von trans‐[PtCl2(NH3)(N‐Glycin)]⋅H...
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