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A copper(II) complex [Cu(μ-1,3-N 3 )(N 3 )(bpp)] n (1) (bpp=1,3-bis(4′-pyridyl)propane) has been shown to exhibit a two-dimensional network formed by the bpp ligands interlinking copper(II)-azido chains, in which the single azido bridge assumes an asymmetric μ-1,3 mode and mediates weak ferromagnetic coupling. On the other hand, the reaction of cobalt(II), azido and bpp yielded...
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