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Mixed oxides of titanium with cerium were examined for the impact of their reducible oxide properties as a support for nickel-catalysed low temperature steam reforming of methane. Modifications to characteristics of the mixed oxide supports were obtained by varying the relative cerium/titanium composition and utilising different synthesis routes. Sol-gel and flame spray pyrolysis synthesis techniques...
Active sites responsible for the preferential oxidation of carbon monoxide were investigated using 4wt.% Cu–CeO 2 catalysts prepared by flame spray pyrolysis. Surface redox properties of the catalyst were assessed using a series of temperature-programmed reduction (CO, H 2 and mixed) experiments, as well as operando infrared spectroscopy. It was demonstrated that CO and H 2 ...
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