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The anion coordination complex, [Cl⊂Pt(bpt)4]Cl (bpt=N,N′-bis(3-pyridylmethyl)-2-thiourea), was synthesized and studied by X-ray crystal structure analysis, NMR and FAB mass spectra. In the solid state, the Pt(bpt)4 anion receptor adopts a cone conformation to bind the chloride anion through hydrogen bonds and electrostatic interaction in which the four branches of the thiourea ligands bind the chloride...
A 3D sodium(I) complex driven by the coordination bonds and a 3D hydrogen-bond-sustained network, with empirical formulae [Na 2 (3,5-pdc)(H 2 O) 4 ] n (1) and [Na 2 (4-pc) 2 (H 2 O) 8 ] n (2), respectively, have been synthesized and characterized. X-ray single crystal determination of 1 reveals that two types of hexa-coordinate...
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