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A novel one-dimensional nickel(II) complex incorporating a nitroxide radical with the formula {[Ni(NITpPy) 2 (TCB)(H 2 O) 2 ]·2H 2 O} n (NITpPy=2-(4 ′ -pyridyl)-4,4,5,5-tetramethyl-imidazoline-1-oxyl-3-oxide and TCB=1,4-dicarboxy-2,5-dicarboxylatobenzene dianion) has been synthesized and characterized. Theoretical analysis of the variable-temperature...
A dithiooxalato-bridged manganese(II)-nickel(II) bimetallic complex : [MnNi(C 2 O 2 S 2 ) 2 (H 2 O) 3 ] · 4H 2 O has been prepared and its crystal structure determined. It consists of one-dimensional chains in which alternating Mn(II) and Ni(II) ions are bridged by C 2 O 2 S 2−2 ligands. The coordination environment...
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