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Enzymatic glycosidation using sugar oxazolines 1–3 having a carboxylate group as glycosyl donors and compounds 4–6 as glycosyl acceptors was performed by employing a chitinase from Bacillus sp. as catalyst. All the glycosidations proceeded with full control in stereochemistry at the anomeric carbon of the donor and regio-selectivity of the acceptor. The N,N′-diacetyl-6′-O-carboxymethylchitobiose oxazoline...
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