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A fluorescence and absorption chemosensor (SAAT) based on 5‐(hydroxymethyl)‐salicylaldehyde (SA) and o‐aminothiophenol (AT) was designed and synthesized. SAAT in DMSO–HEPES (20.0 mM, v/v, 1:99, pH = 7.0) solution shows a highly selective and sensitive absorption and an ‘on–off’ fluorescence response to Cu2+ ions in aqueous solutions over all other competitive metal ions including Na+, Ag+, Ba2+, Ca...
Here, to elucidate the interaction mechanism and physicochemical properties of remimazolam and human serum albumin interactions, techniques such as fluorescence, circular dichroism (CD) spectroscopy, and isothermal titration calorimetry have been applied for study. The thermodynamic parameters at body temperature (ΔS = −207 J·mol−1·K−1, ΔS = −9.76 × 104 J·mol−1 and ΔG = −3.34 × 104 J·mol−1; 310 K)...
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