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A new route to α,ω‐diene urethane monomer is proposed by converting 10‐undecenoic acid into the corresponding acyl azide, followed by urethanization with 10‐undecenol. ADMET polymerizations of this α,ω‐diene urethane monomer as well as other bio‐based α,ω‐dienes bearing various organic functions (ester, carbonate, ether, amide) were carried out in bulk and solution conditions. A screening of the most...
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