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HF-EPR spectroscopy studies performed, with frequencies in the 100 to 500 GHz range and at low temperatures, on tyrosyl radicals from Ribonucleotide Reductase as well as on Fe(III) complexes are presented. For spin 1/2 systems, HF-EPR is used to resolve the g-anisotropy. For metal ions, with S>1/2, high frequencies are used to determine the Zero-Field Splitting parameters. A few different limiting...
Written by the leading experts in the field, this book describes the development and current state-of-the-art in single molecule spectroscopy. The application of this technique, which started 1989, in physics, chemistry and biosciences is displayed.
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