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The effects of various components in an emulsion polymerization system on the dissociation rate coefficient of persulfate at 50°C are examined using iodometry. Styrene monomer is found to enhance greatly the dissociation, while there is either no effect or possibly a slightly reduced rate of dissociation with methyl methacrylate monomer. The saturated analogues of these monomers (ethylbenzene and...
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