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In the spectrum of uniformly 15 N-labeled cytochromec 3 , the relative linewidths of the doublet peaks of the 15 N-coupled imido proton of the coordinated imidazole group were reversed on oxidation. This inversion was explained by the interference relaxation process between the electron–proton dipolar and 15 N– 1 H dipolar interactions. The inversion can be...
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