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Simulation of the high-field EPR spectra from spin-labelled lipids in membranes is treated. The lateral ordering of the lipid chains is characterised by gxx−gyy anisotropy and can be analysed by motional narrowing theory. Spin Hamiltonian tensors required for simulation must be corrected for changes in environmental polarity within...
The dynamics and environment of sphingomyelin spin-labelled at different positions in the N-acyl chain have been studied in dimyristoyl phosphatidylcholine bilayer membranes by using electron spin resonance spectroscopy. Comparison was made with phosphatidylcholine spin-labelled on the sn-2 acyl chain in the same host membrane. Spin-labelled sphingomyelin was found to mix well with the host phosphatidylcholine...
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