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A crystal structure of dimerized 1,3-diisopropyl carbodiimide (CDI) has been obtained and its synthesis through a reaction of CDI with aluminum chloride (AlCl3) has been studied. It possesses space group P21/c, with a = 9.352(5), b = 7.956(4), c = 11.405(6) Å and β = 112.465(5)°. It has been observed that this reaction is catalytic with respect to AlCl3. Kinetic studies of the dimer show that its...
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