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Thermoresponsive nanoparticles (NPs) represent an important hybrid material comprising functional NPs with temperature‐sensitive polymer ligands. Strikingly, significant discrepancies in optical and catalytic properties of thermoresponsive noble‐metal NPs have been reported, and have yet to be unraveled. Reported herein is the crafting of Au NPs, intimately and permanently ligated by thermoresponsive...
In situ precision synthesis of monodisperse hairy plasmonic nanoparticles with tailored dimensions and compositions by capitalizing on amphiphilic star‐like diblock copolymers as nanoreactors are reported. Such hairy plasmonic nanoparticles comprise uniform noble metal nanoparticles intimately and perpetually capped by hydrophobic polymer chains (i.e., “hairs”) with even length. Interestingly, amphiphilic...
Monodisperse hairy plasmonic nanoparticles with precisely‐controlled dimensions and compositions are synthesized by G. Zhang, Z. Lin, and co‐workers on page 6714, using well‐defined amphiphilic star‐like diblock copolymers as nanoreactors. In contrast to nanoparticles traditionally capped with small ligands, such hairy plasmonic nanoparticles show superior stability owing to the protection from permanently...
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