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Ge-doped Li 7 La 3 Zr 2 O 12 (LLZ) is prepared via the conventional solid-state reaction. Our results showed that doping Ge of less than 1 wt% could stabilize the cubic phase of garnet-type LLZ and also increase its ionic conductivity up to 8.28×10 −4 S/cm at room temperature. When the content of Ge dopant is higher, GeO 2 impurity phase would appear...
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