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New oxidovanadium(IV) complexes with a modification of the ligand in the VO2+ coordination sphere were synthesized. [VO(mIDA)(dmbipy)]∙1.5H2O and [VO(IDA)(dmbipy)]∙2H2O were obtained as dark green crystals and grey-green powder, respectively (mIDA = N-methyliminodiacetic anion, IDA = iminodiacetic anion, dmbipy = 4,4′-dimethoxy-2,2′-dipyridyl). The crystal structure of [VO(mIDA)(dmbipy)]·1.5H2O has...
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