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Three new zinc(II) and cadmium(II) silanethiolate complexes [Zn{SSi(OtBu) 3 } 2 (μ-bpea)⋅CH 3 CN] n 1, [Cd{SSi(OtBu) 3 } 2 (μ-bpea)⋅2CHCl 3 ] n 2 and [Cd{SSi(OtBu) 3 } 2 (μ-bpey)⋅C 7 H 8 ] n 3 with two bypiridine derivatives, [bpea=1,2-bis(4-pyridyl)ethane and bpey=1,2-bis(4-pyridyl)ethylene] have...
Ln(III) ions, where Ln(III)=Eu and Tb, were complexed with 2,2′-bipyridine N,N′-dioxide (bpyO 2 ) as a ligand. To the coordination sphere were introduced coligands such as 1,10-phenanthroline (phen), triphenylphosphine oxide (TPPO), salicylic acid (SA) and phthalic acid (PA) to substitute water molecules (O–H quenching oscillators) from the nearest environment of the central ion. These Ln(III)...
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